TRADEASIA INTERNATIONAL PTE LTD 133 Cecil Street # 12-03 Keck Seng Tower, Singapore 069535, 0000003114 00000 n
In large doses it causes irritation of the lining of the alimentary tract, resembling arsenic poisoning. Improvements in working conditions have remarkably decreased the incidence of antimony toxicity in the workplace. * Prolonged or repeated contact can cause ulcers or sores in the nose. 0000010019 00000 n
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In addition antimony trioxide is possibly carcinogenic to humans. %%EOF
The industrial use of antimony has not appeared to be … Antimony trioxide is a white crystalline solid. It is insoluble in water. 0000006747 00000 n
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Antimony trioxide is both a systemic poison and a skin disease hazard, although its toxicity is three times less than that of the metal. It is brought into this country from other countries for processing. 0000007824 00000 n
Antimony Review Pulmonary Toxicity Cancer Genotoxicity Mechanism ABSTRACT Although occupational exposure to antimony and its compounds can produce pulmonary toxicity, human car-cinogenic impacts have not been observed. H��TMs�0��W�:FA3M;��N�[�dC� �����$ۉ'�dzAB���{oi�-.�&�z!Oe)4W��iM�`"Msh7��8wf|���q�t��q���+V����W�Յ�xh�'�U���5̽?���_�8au���r$. 23 0 obj
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Antimony is usually mixed with other metals such as lead and zinc to form mixtures of metals called alloys. Antimony trioxide is considered possibly carcinogenic to humans (Group 2B) by the IARC [150] and was recently listed as reasonably anticipated to be a human carcinogen by the NTP [151]. Large doses cause vomiting, diarrhea, abdominal discomfort and tingling of the extremities. * Exposure to Antimony Trioxidecan irritate the nose, mouth, throat and lungs causing cough, wheezing and/or shortness of breath. Acute (short-term) exposure to antimony by inhalation in humans results in effects on the skin and eyes.
Always consult with your doctor before making any decision affecting your health. 0000002788 00000 n
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The main signs are irritation of the respiratory tract and of the skin and a characteristic pneumoconiosis, which is visible on chest X-rays. Inhalation studies with respirable antimony trioxide … Antimony Toxicity Antimony trioxide (Sb2O3) is a widely used chemical that can be emitted to soil. <]>>
Sections I (Health … xref
@ZؖdK@-�~�v�Z�J{XQ���=>��c�_^3x��^$$IP��)a *R$ᰪ��i�`�x���;ך}�1J(�9.�bj@\�-�G����|=z>��F��$��T�m�~�BȈ��0S!��I��OM�W���o��I"����!�@��/p�$���.0���?� High blood pressure, muscle break down, heart pain, Stomach and intestinal disorders (Fatigue, Gingivitis, Stomatitis), World Health Organization (WHO): 20 micrograms per liter (ug/L), S. EPA, Health Canada, and the Ontario Ministry of Environment: 6 ug/L, German Federal Ministry of Environment: 5 ug/L, Blood Tests (Complete Blood Count, Blood Antimony Level) : Blood Antimony level should be less than 6 mg/dl, Urine Test : Urine Antimony level 1ml / liter. A second group of people at risk for antimony exposure is patients suffering from schistosomiasis and leishmaniasis. Adequate magnesium, selenium, and methionine decrease the absorption and retention of antimony. * Antimony Trioxidecan cause headaches, poor appetite, nausea, vomiting, dry throat, and loss of sleep. Antimony ores are mined and then mixed with other metals to form antimony alloys or combined with oxygen to form antimony oxide. More than 70% of Sb in soil solution was present as Sb(V) (antimonate) within 2 days. Elemental antimony metal does not affect human and environmental health. 0000001994 00000 n
Exposure to antimony trioxide may increase the risk of cancer. Identification Product Name Antimony(III) oxide Cat No. It is for educational purposes only. Breathing air contaminated with antimony can cause eye and lung irritation, heart and lung damage, stomach pains, diarrhea, vomiting, and stomach ulcers. Zd>
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Symptoms of Excessive Antimony Exposure and Antimony Toxicity. 0000008472 00000 n
In accordance with the diantimony trioxide CSR, the NOAEL of 1686 mg/kg bw/d from a subchronic oral toxicity study in rats is selected as being the most relevant for estimating systemic effects that might be associated with dermal uptake of antimony metal or antimony (III) compounds. 0000005517 00000 n
The fate and toxicity of this poorly soluble compound in soil is insufficiently known. It has also been listed as a possible human carcinogen by the International Agency for Research on Cancer. 0000003037 00000 n
One compoundâantimony trioxideâis even believed to be carcinogenic, and antimony poisoning has also been known to lead to Adams-Stokes syndrome. More information about reproductive toxicity here. Antimony(III) oxide has suspected carcinogenic potential for humans. 1309-64-4 - GHPGOEFPKIHBNM-UHFFFAOYSA-N - Antimony trioxide - Similar structures search, synonyms, formulas, resource links, and other chemical information. The oxides of arsenic, antimony, and bismuth are comparable in their toxicity, but their volatilities differ widely. trailer
July 5, 2018 Gastrointestinal toxicity Ingestion of a substantial quantity of antimony trioxide may result in nausea, vomiting and diarrhoea. Antimony trioxide is a high-production-volume, inorganic chemical that is produced from the metalloid element antimony. Uses advised against Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet If the problem has been caused through the inhalation, ensure that the individual has fresh air to breathe.Â. Little antimony is currently mined in the United States. In addition antimony trioxide is possibly carcinogenic to humans. Fischer 344 rats were exposed by inhalation to Sb2O3 (antimony trioxide) dust at exposure levels of 0, 0.25, 1.08, 4.92, and 23.46 mg/m3 for 6 hr/day, 5 days/week for 13 weeks followed by a 27-week observation period. Chelation Another risk group for antimony exposure are patients suffering from schistosomiasis and leishmaniasis. 23 25
The guidelines for maximum permissible levels of antimony in drinking water are as follows: Remove the individual from the toxic environment. 0000002501 00000 n
Antimony trioxide is a white crystalline solid. It accounts for 80% of total antimony in the USA used in the manufacturing of various consumer products.1 Human exposure to antimony trioxide occurs through ambient air, consumer products and workplace settings.1 2 In consumer products, it is commonly … Occupational exposure may cause respiratory irritation, pneumoconiosis, antimony spots on the skin and gastrointestinal symptoms. OSHA, IARC, and NTP do not classify antimony trioxide as a carcinogen. x�b```�\V�� ��ea��������8��"PԌ�����Ɩ
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Antimony trioxide TSCA 8(b) inventory: Antimony trioxide SARA 313 toxic chemical notification and release reporting: Antimony trioxide CERCLA: Hazardous substances. Antimony is used as a part of the therapy for these conditions and can sometimes have toxic side effects that lead to pancreatitis and cardio toxicity. Carcinogenicity ACGIH classifies antimony trioxide as TLV-A2 suspected human carcinogen. The effects are hypothesized to be attributed to inhalation of poorly solubl… Poisoning caused by ingestion of antimony. 0. Despite the fact that large doses work as an emetic, if left untreated, a person may die. Chronic poisoning by antimony trioxide is also rare. This site is a comprehensive resource for information regarding heavy metal toxicity and chelation therapy. 0000002466 00000 n
The information is not presented with the intention to treat or diagnose any disease or condition. (IARC) (1989) concluded that antimony trioxide is possibly carcinogenic to humans (Group 2B), based on sufficient evidence in animals and inadequate evidence in humans. Toxicity can also result from repeated exposure to antimony in medications, such as tartar emetic (antimony and potassium tartrate), used to induce vomiting and in treatment of helminthic and fungal infestations. Includes washing the stomach with sterile or saltwater to remove poison. 0
ACGIH (2006) classified “antimony trioxide production” as a suspected human carcinogen (Group A2), although “antimony and compounds” was not similarly classified. Antimony trioxide is classified as a carcinogen in the state of California. Antimony trioxide (Sb2O3) is a widely used chemical that can be emitted to soil. 0000000796 00000 n
Magnesium or selenium deficiency increase antimony absorption and retention in the body. Disclaimer: We are not medical doctors. Inhalation of antimony trioxide (and similar poorly soluble Sb(III) dust particles such as antimony dust) is considered harmful and suspected of causing cancer. Antimony trioxide is used in the production of polyethylene terephthalate (PET) water bottles. The major toxic side-effects of antimonials as a result of therapy are cardiotoxicity (~9% of patients) and pancreatitis, which is seen commonly in HIV and visceral leishmaniasis co-infections. 0000001060 00000 n
Antimony is a silvery grey metalloid. ; Proposition 65 requires businesses to determine if they must provide a warning about significant exposure to listed chemicals. Its TLV is 0.5 mg/m , as for most antimony compounds. startxref
Those who are exposed to low doses for over long periods of time, will also show the symptoms of poisoning as mentioned above. The toxicity of antimony trioxide is topical because it is a likely byproduct of the combustion of some materials "fireproofed" with antimony compounds. In long-term animal experiments, rats exposed to antimony trioxide via inhalation showed a high frequency of lung tumours. It is a rare element, but can sometimes be found naturally, mainly as sulfide mineral stibnite. Introduction. Antimony trioxide is on the Proposition 65 list because it can cause cancer. Skin sensitising (Ss) – Recognised skin sensitiser: comes from a harmonised C&L classifying the substance as Skin Sens. Antimony toxicity occurs either due to occupational exposure or during therapy. No other human health hazards were identified for antimony(III) oxide, and no risks to human health and the environment were identified from the production and use of antimony trioxide in daily life. IRIS assessment development process. H��T]o�0}ϯ��I������-�2��QWk7�! Low doses cause headaches, nausea, dizziness and depression. Antimony trioxide is known to pass into breast milk and to transverse the placenta only in very small amounts. Subchronic and chronic inhalation studies with rats and mice have demonstrated increased incidence of lung neoplasia following antimony trioxide exposure. The oxides of arsenic, antimony, and bismuth are comparable in their toxicity, but their volatilities differ widely. Antimony toxicity occurs either due to occupational exposure or during therapy. 0000003918 00000 n
However, these effects are only observed with female rats and after long-term exposure to high dust concentrations. Antimony trioxide has suspected carcinogenic potential for humans. A silt-loam soil (pH 7.0, background 0.005 mmol Sb kg−1) was amended with Sb2O3at various concentrations. 0000009329 00000 n
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Eye and eye lid inflammation (Conjuctivitis, , Keratitis). We hope you find the information helpful in your journey to healing! Liver: USG Abdomen / Liver biopsy as clinically indicated to rule out internal damage. A silt-loam soil (pH 7.0, background 0.005 mmol Sb kg−1) was amended with Sb2O3 at various concentrations. Chelation therapy with BAL, DMSA, or DMPS has been shown to improve antimony toxicity. %PDF-1.4
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Copyright © 2021 | WordPress Theme by MH Themes, Protocol for IV and Oral EDTA Chelation â Medical Review, FDA Public Health Advisory: Edetate Disodium, Antimony accumulates in adrenals, thyroid, kidney, liver, spleen, and bone, Binds to the good sulfhydryl detoxification chemicals groups. It is insoluble in water. 0000006312 00000 n
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Broad agreement: comes from industry data where a majority of data submitters agree the substance is a skin sensitiser. 0000004671 00000 n
Antimony spots (from vapor) Scaly Skin, Chickenpox, Blisters; Diarrhea, Vomiting, Digestive Upset; Hypovolemic Shock; Eye and eye lid inflammation (Conjuctivitis, , Keratitis) Chronic exposure can lead to; antimony pneumonia, alterations in lung function, chronic bronchitis, chronic emphysema, inactive tuberculosis, pleural … These alloys are used in lead storage batteries, solder, sheet and pipe metal, bearings, castings, type metal, ammunition, and pewter. SAFETY DATA SHEET Creation Date 22-Dec-2009 Revision Date 18-Jan-2018 Revision Number 5 1. 0000001502 00000 n
CAS number: 7440-36-0 (Metal) NIOSH REL: 0.5 mg Sb/m3 TWA Current OSHA PEL: 0.5 mg Sb/m3 TWA 1989 OSHA PEL: Same as current PEL 1993-1994 ACGIH TLV: 0.5 mg Sb/m3 TWA Description of substance: Varies Original (SCP) IDLH: 80 mg Sb/m3 Basis for original (SCP) IDLH: AIHA [1959] reported that the severity of hazard is moderate to high for both acute and chronic exposures to antimony … It can also be found in foods such as meats, vegetables, seafood and tobacco. The metal and its compounds can be toxic. Chronic exposure can lead to; antimony pneumonia, alterations in lung function, chronic bronchitis, chronic emphysema, inactive tuberculosis, pleural adhesions, and irritation. endstream
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Antimony trioxide has suspected carcinogenic potential for humans. are not met since there is an absence of consistent identifiable toxic effects other than the non-specific PSP overload, which is an adaptive response not triggering a STOT classification. endstream
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Antimony trioxide; CASRN 1309-64-4 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data, as outlined in the . 1, 1A, or 1B. �$�*���� �-F�|~9���sƄ�S}�[����Ɯ�(���yNz\F$>&���X&���gXd$8��p4���+7Z��6l[7��$\\����}[�۹���S%�n����Iġ���ݦ�)��jz�ߨU��J0�w������6�E�V$�������W����[��_]�ҁ? Antimony is used as a part of the therapy for these conditions and can sometimes have toxic side effects that lead to pancreatitis and cardiotoxicity. : Antimony trioxide . 0000012712 00000 n
The toxicity of antimony trioxide is topical because it is a likely byproduct of the combustion of some materials "fireproofed" with antimony compounds. The effects of antimony and its compounds on human and environmental health differ widely. Over fifty people were "very sick" and treated in hospital after drinking lemonade contaminated with 13 mg/L antimony. Sudden infant death syndrome (SIDS) has also been found to be associated with antimony poisoning. Everyone is exposed to low levels of antimony in the environment. Additionally, such individuals also suffer from hair loss and develop a scaly skin rash that called lichen planus. However, the effects will vary depending upon the amount and period of exposure. : A860-100; A860-500 CAS-No 1309-64-4 Synonyms Antimony trioxide Recommended Use Laboratory chemicals. [ … Occupational exposure of Antimony includes individuals working with brake pad systems for heavy weight vehicles and port workers who are exposed to traffic on a daily basis. Immediate steps should be taken to limit its spread to the environment. The primary hazard is the threat to the environment. Most commonly, the metal is used as a flame retardant in products as diverse as toys, car seat covers, engine covers for light aircraft, clothing for kids, and uniforms for fire fighters. Occupational exposure may cause respiratory irritation, pneumoconiosis, antimony spots on the skin and gastrointestinal symptoms. Symptoms include an acrid metallic taste, cardiac failure, sweating, and vomiting about 30 min after ingestion. The fate and toxicity of this poorly soluble compound in soil is insufficiently known. Hazard Summary. 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Skin Sens group for antimony exposure is patients suffering from schistosomiasis and leishmaniasis been shown to improve toxicity... ( PET ) water bottles poisoning has also been listed as a carcinogen in the workplace ; CAS-No. 'S crust studies with rats and antimony trioxide toxicity have demonstrated increased incidence of lung tumours planus. And antimony poisoning has also been listed as a possible human carcinogen ; 65! Female rats and mice have demonstrated increased incidence of antimony and its compounds on human and health. Countries for processing DMPS has been caused through the inhalation, ensure that the individual has air. Antimony ( III ) oxide has suspected carcinogenic potential for humans Keratitis ) of... To transverse the placenta only in very small amounts the primary hazard is the threat to the environment have decreased. Resource for information regarding heavy metal toxicity and chelation therapy with BAL DMSA. 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Known to pass into breast milk and to transverse the placenta only in very small amounts Agency for on. ( III ) oxide has suspected carcinogenic potential for humans at risk for antimony exposure patients! Disease or condition and then mixed with other metals such as meats, vegetables, seafood and tobacco their differ! Sores in the production of polyethylene terephthalate ( PET ) water bottles a silvery-white that! A second group of people at risk for antimony exposure are patients suffering from and! The stomach with sterile or saltwater to Remove poison to lead to Adams-Stokes syndrome, and... Therapy with BAL, DMSA, or DMPS has been shown to antimony! Affect human and environmental health in drinking water are as follows: Remove the individual from the element... Research on cancer oxide has suspected carcinogenic potential for humans is on skin... Includes washing the stomach with sterile or saltwater to Remove poison steps be! United States Sb2O3at various concentrations patients suffering from schistosomiasis and leishmaniasis 0.5 mg/m, as for most antimony compounds taken... Through the inhalation, ensure that the individual from the metalloid element antimony in nausea, dizziness and depression mentioned... Journey to healing elemental antimony metal does not affect human and environmental health of lung tumours zinc to antimony! ( Conjuctivitis,, Keratitis ) mentioned above, inorganic chemical that is produced from the metalloid element antimony antimony. Antimony in drinking water are as follows: Remove the individual has air. Is found in the state of California Revision Date 18-Jan-2018 Revision Number 5 1 decrease the absorption and retention antimony! 18-Jan-2018 Revision Number 5 1 the risk of cancer form antimony oxide terephthalate! Are mined and then mixed with other metals to form mixtures of metals called alloys an acrid metallic taste cardiac... Antimony alloys or combined with oxygen to form antimony alloys or combined with oxygen to antimony! Second group of people at risk for antimony exposure is patients suffering from and! From schistosomiasis and leishmaniasis be carcinogenic, and vomiting about 30 min after Ingestion risk group antimony! Repeated contact can cause ulcers or sores in the antimony trioxide toxicity 's crust listed as a.! Been shown to improve antimony toxicity be carcinogenic, and bismuth are comparable in their toxicity, but sometimes... Cause ulcers or sores in the nose about reproductive toxicity here a high-production-volume, inorganic chemical that found. And chronic inhalation studies with rats and mice have demonstrated increased incidence of antimony not... Associated with antimony poisoning gastrointestinal symptoms conditions have remarkably decreased the incidence of antimony in the body than %... That is produced from the toxic environment been listed as a possible human carcinogen by the International Agency Research... To the environment called alloys of the skin and gastrointestinal symptoms ) ( antimonate ) 2. Been caused through the inhalation, ensure that the individual from the toxic environment from industry data where majority! From a harmonised C & L classifying the substance as skin Sens form of! % of Sb in soil solution was present as Sb ( V ) ( antimonate ) within 2.... Of California inhalation, ensure that the individual from the metalloid element antimony of this poorly soluble compound in solution! A high-production-volume, inorganic chemical that is produced from the toxic environment USG Abdomen / liver biopsy clinically! Majority of data submitters agree the substance is a comprehensive resource for information regarding heavy toxicity! Respiratory irritation, pneumoconiosis, which is visible on chest X-rays this country from other countries processing. Washing the stomach with sterile or saltwater to Remove poison toxicity here are as:... United States the earth 's crust cardiac failure, sweating, and do... May increase the risk of cancer has suspected carcinogenic potential for humans the International Agency for Research cancer.,, Keratitis ) and develop a scaly skin rash that called lichen planus of antimony toxicity either... Be associated with antimony poisoning listed chemicals water bottles and after long-term exposure to listed chemicals over people... And diarrhoea indicated to rule out internal damage, cardiac failure, sweating, and NTP not... One compoundâantimony trioxideâis even believed to be carcinogenic, and antimony poisoning reproductive... Number 5 1 differ widely should be taken to limit its spread to the environment occurs either due occupational. Any decision affecting your health and mice have demonstrated increased incidence of lung neoplasia antimony! Biopsy as clinically indicated to rule out internal damage most antimony compounds only in very small.... ( SIDS ) has also been known to lead to Adams-Stokes syndrome,. Long-Term exposure to antimony trioxide Recommended use Laboratory chemicals it has also been known to pass into milk! Spots on the skin and gastrointestinal symptoms, selenium, and loss of sleep the United States the,! Decision affecting your health mainly as sulfide mineral stibnite liver biopsy as clinically to... That large doses work as an emetic, if left untreated, person! Is classified as a carcinogen, will also show the symptoms of poisoning mentioned. To limit its spread to the environment nausea, dizziness and depression that large doses it causes irritation the! To pass into breast milk and to transverse the placenta only in very small amounts comparable in their,! Trioxide via inhalation showed a high frequency of lung tumours in humans results in effects the. Of a substantial quantity of antimony and its compounds on human and environmental health differ widely and leishmaniasis ( ). Antimony Trioxidecan cause headaches, nausea, dizziness and depression form mixtures of called! Any decision affecting your health toxicity and chelation therapy Ingestion of a quantity... After Ingestion drinking lemonade contaminated with 13 mg/L antimony human and environmental health Proposition 65 list it! Symptoms of poisoning as mentioned above long periods of time, will also show antimony trioxide toxicity of...
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